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Macromolecules版 - Monomer distribution
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话题: monomer话题: nafion话题: ab话题: 30mer
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1 (共1页)
C***S
发帖数: 175
1
Say, in random polymer AB, what is the probability of 30mer,
P^30, if the reactivity of either of is P.
Any paper talking about this, Book is also good.
Thanks!
w********h
发帖数: 12367
2
if polycondensation (yes for your assumption "random"),
you can find the calculation in any polymer textbook on step-polymerization.
here is one practical example of AA, B1B1, and B2B2:
OSAHENI JA, JENEKHE SA
ELECTROACTIVE AND PHOTOACTIVE ROD-COIL COPOLYMERS - DESIGN, SYNTHESIS, AND
SUPRAMOLECULAR REGULATION OF PHOTOPHYSICAL PROPERTIES
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 117 (28): 7389-7398 JUL 19 1995
Times Cited: 66
I also published one paper on a more complicated AA, BB, AB case.
However

【在 C***S 的大作中提到】
: Say, in random polymer AB, what is the probability of 30mer,
: P^30, if the reactivity of either of is P.
: Any paper talking about this, Book is also good.
: Thanks!

C***S
发帖数: 175
3
Thanks.
My purpose is to calculate the TFE sequence length in Nafion, which
is crucial for the crystalization of Nafion.
Based on this, we can cooperate our NMR data to propose a reasonable
morphology of Nafion.

【在 w********h 的大作中提到】
: if polycondensation (yes for your assumption "random"),
: you can find the calculation in any polymer textbook on step-polymerization.
: here is one practical example of AA, B1B1, and B2B2:
: OSAHENI JA, JENEKHE SA
: ELECTROACTIVE AND PHOTOACTIVE ROD-COIL COPOLYMERS - DESIGN, SYNTHESIS, AND
: SUPRAMOLECULAR REGULATION OF PHOTOPHYSICAL PROPERTIES
: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 117 (28): 7389-7398 JUL 19 1995
: Times Cited: 66
: I also published one paper on a more complicated AA, BB, AB case.
: However

1 (共1页)
进入Macromolecules版参与讨论
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相关话题的讨论汇总
话题: monomer话题: nafion话题: ab话题: 30mer