d**a 发帖数: 3715 | 1 If my monomer (aromatic compound) has a very poor solubility in THF or
toluene, then how it can be polymerized? |
m*****e 发帖数: 1506 | 2 try polar solvents like DMF or DMSO
try polymerization at high temperature
it also depends on what kind of monomer and what kind of polymerization. |
d**a 发帖数: 3715 | 3 Thank you for your reply. The monomer is a multi-ring aromatic compound,
very difficult to dissolve in DMF at 80 oC.
I am currently trying a free radically polymerization process. |
c*s 发帖数: 2145 | 4 sounds like steric effect plays a role and you might try copolymerize with
other monomer
【在 d**a 的大作中提到】 : Thank you for your reply. The monomer is a multi-ring aromatic compound, : very difficult to dissolve in DMF at 80 oC. : I am currently trying a free radically polymerization process.
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t***u 发帖数: 20182 | 5 how did u purify it? it has poor solubility in any solvent? |
m*****e 发帖数: 1506 | 6 You may want to modifiy your monomer, re-link the vinyl group and pendant
functional group of your monomer using a longer spacer,and also try to redue
the rigidity of your monomer structure.
【在 d**a 的大作中提到】 : Thank you for your reply. The monomer is a multi-ring aromatic compound, : very difficult to dissolve in DMF at 80 oC. : I am currently trying a free radically polymerization process.
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d**a 发帖数: 3715 | 7 en,make sense. Previously this monomer has been successfully copolymerized
with styrene in a molar ratio of 50/50. I will try a living polymerization
to see what will happen.
【在 c*s 的大作中提到】 : sounds like steric effect plays a role and you might try copolymerize with : other monomer
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a*****h 发帖数: 13 | 8 maybe you can use benzene
but that is toxic... |